| 127 | 0 | 23 |
| 下载次数 | 被引频次 | 阅读次数 |
为提高超疏水锦纶织物的耐久性，以硬脂酸对蒙脱土(MMT)进行表面改性，再与聚二甲基硅氧烷(PDMS)混合制成分散液。采用浸涂法将分散液涂在锦纶织物表面，从而制得具有耐磨性的超疏水锦纶织物。使用红外光谱(FTIR)和扫描电镜(SEM)对织物化学成分以及表面形貌进行表征，并研究MMT与PDMS的质量比对锦纶织物疏水性能和耐磨性能的影响。试验结果显示，当MMT与PDMS的质量比为0.75∶1时，织物表面接触角最高，可达153.6°。该织物经砂纸摩擦55 cm后仍能保持超疏水性，显示出较好的耐摩擦性能。此外，该超疏水锦纶织物不仅具有良好的耐酸、耐弱碱及抗紫外线性能，还具有良好的自清洁性能。
Abstract：To enhance the durability of superhydrophobic nylon fabrics, montmorillonite(MMT) was modified with stearic acid and subsequently blended with polydimethylsiloxane(PDMS) to formulate a functional dispersion. The dispersion was applied to nylon fabric surfaces via dip-coating, producing abrasion-resistant superhydrophobic textiles. Fourier-transform infrared spectroscopy(FTIR) and scanning electron microscopy(SEM) were employed to analyze chemical compositions and surface morphologies. The influence of MMT/PDMS mass ratios on hydrophobicity and abrasion resistance was systematically investigated. Optimal performance was observed at a 0.75∶1 MMT/PDMS ratio, achieving a maximum contact angle of 153.6°. The modified fabric retained superhydrophobicity after 55 cm of sandpaper abrasion, demonstrating exceptional wear resistance. Additionally, the treated fabric exhibited acid resistance, weak alkali tolerance, UV stability, and effective self-cleaning properties.
[1] ZHAO W J,XIAO X Y,PAN G M,et al.Fabrication of superhydrophobic cotton fabric treated with n-dodecyltrimethoxysilane/zirconium oxychloride for highly efficient oil/water separation[J].Journal of Coatings Technology and Research,2020,17(3):657-668.
[2] JIANG S S,DIAO Y H,YANG H G.Recent advances of bio-inspired anti-icing surfaces[J].Advances in Colloid and Interface Science,2022,308:102756.
[3] SEYED V R,ALI M,ALI N,et al.Drag reduction in internal turbulent flow by fabricating superhydrophobic Al2O3/waterborne polyurethane coatings[J].Surface and Coatings Technology,2021,421:127406.
[4] TELMENBAYAR L,GOPAL R A,YANG D,et al.Development of mechanically robust and anticorrosion slippery PEO coating with metal-organic framework (MOF) of magnesium alloy[J].Chemical Engineering Journal,2023,458:141397.
[5] WU P,ZHANG B,NAI X Y,et al.Durable self-cleaning superhydrophobic coatings based on 5 Mg(OH)2·MgSO4·2H2O whisker-SiO2 nanoparticles composites[J] Applied Surface Science,2023,622:156940.
[6] 王婵铭，杨文芳，丰万齐.仿生超疏水表面的研究及其在纺织领域的应用[J].纺织科技进展，2018(11):1-5.
[7] 滕福康，王含，周子恒，等.超疏水防覆冰涂层的研究进展[J].西部皮革，2020,42(3):99.
[8] SANJEEV P D,MOHAMED A S A,SANJAY S L,et al.Recent advances in durability of superhydrophobic self-cleaning technology:A critical review[J].Progress in Organic Coatings,2020,138:105381.
[9] LI X Y,YANG K L,YUAN Z Q,et al.Recent advances on the abrasion resistance enhancements and applications of superhydrophobic materials[J].The Chemical Record,2023,23(4):e202200298.
[10] WANG D H,SUN Q Q,HOKKANEN M.J,et al.Design of robust superhydrophobic surfaces[J].Nature,2020,582:55-59.
[11] LIU B,YAN S M,HE Y.Research for electrodeposited superhydrophobic Ni-W-WS2 coating and its anticorrosion and wear resistance [J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2022,655:130236.
[12] 刘君仪，冯庆革，陈考，等.模板法制备多孔超疏水SiO2/PDMS海绵及油水分离应用[J].无机盐工业，2024,56(5):45-52.
[13] 胥家辉，郭肖青，王伟，等.海藻酸钠/纳米蒙脱土纤维制备及其增强增韧机制[J].纺织学报，2024,45(6):16-22.
[14] WANG S T,LIU K S,YAO X,et al.Bioinspired surfaces with superwettability:New insight on theory,design,and applications[J].Chemical Reviews,2015,115:8230-8293.
[15] ZHAO J C,ZHANG T,LI Y M,et al.Fluorine-free,highly durable waterproof and breathable fibrous membrane with self-clean performance[J].Nanomaterials,2023,13(3):516.
基本信息:
DOI：10.19507/j.cnki.1673-0356.2025.03.001
中图分类号:TS195.5
引用信息:
[1]吴锐,王伟杰,熊固等.含蒙脱土耐磨超疏水锦纶织物的制备[J].纺织科技进展,2025,47(03):43-47.DOI:10.19507/j.cnki.1673-0356.2025.03.001.
基金信息:
西安工程大学大学生创新创业训练计划项目(S202310709101)