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采用载铜分子筛抗菌剂与聚酰胺(PA6)切片共混,再通过熔融纺丝制备载铜分子筛-PA6抗菌纤维;借助台式扫描电子显微镜、单纤维强力仪、差示扫描热量仪及热重分析仪等分析不同含量的载铜分子筛对PA6纤维表面形貌及力学性能的影响,并对比测试水洗10次前后载铜分子筛-PA6纤维的抗菌性能。结果发现,载铜分子筛均匀地分散在PA6纤维中,与PA6纤维结合良好并能发挥抗菌作用。随着载铜分子筛含量的增加,载铜分子筛-PA6纤维的热稳定性保持良好,断裂伸长率先增加后缓慢减小。当载铜分子筛含量为0.50%时,载铜分子筛-PA6纤维对金黄色葡萄球菌和大肠杆菌的抑菌率分别为98.20%和94.00%。水洗10次后,载铜分子筛-PA6纤维对这2种菌的抑菌率未发生明显下降。
Abstract:Copper-loaded molecular sieve antimicrobial agent was blended with polyamide(PA6) slices, and copper-loaded molecular sieve-PA6 antimicrobial fibers were prepared by melt spinning. The effects of copper-loaded molecular sieve content on PA6 fiber surface morphology and mechanical properties were analyzed using a desktop scanning electron microscope, single-fiber tensile tester, differential scanning calorimeter, and thermogravimetric analyzer. Antimicrobial properties were compared between copper-loaded molecular sieve-PA6 fibers before and after 10 washing cycles. Results indicated uniform dispersion of copper-loaded molecular sieves within PA6 fibers, with effective interfacial bonding enabling antimicrobial functionality. Increasing molecular sieve content enhanced thermal stability while elongation at break initially increased then gradually decreased. At 0.50% Cu-loaded molecular sieve content, the fibers exhibited antibacterial rates of 98.20% against E. coli and 94.00% against S. aureus. After 10 washes, inhibition rates against both bacteria showed no significant decrease.
[1] 陈仕国.新型超亲水高分子抗菌剂的分子设计、合成及作用机制研究[Z].深圳:深圳大学,2019-06-18.
[2] 张海涛,张雪,刘蒙蒙,等.天然抗菌纺织品的发展现状[J].纺织科技进展,2020(3):8-11.
[3] 郑晓頔,盛平厚,蒋佳岑,等.铜改性抗菌防螨聚酰胺6纤维的制备及其性能[J].纺织学报,2024,45(3):19-27.
[4] 同黎娜.功能性纤维“花样多”[N].中国纺织报,2023-09-06(002).
[5] 邓通,廖世豪,黄鑫鑫,等.抗菌纱线的研究进展 [J].毛纺科技,2022,50(11):128-133.
[6] 张华.生物医用功能纤维的研究进展及趋势 [J].化工新型材料,2009,37(1):11-13.
[7] 郭盟盟,孟家光.抗菌剂在纤维及织物上的应用[J].纺织科技进展,2012(1):14-16,25.
[8] 李广鲁.纺织品抗菌整理方法研究[J].西部皮革,2020,42(15):133.
[9] 周卫冕,杨群,朱杰,等.光敏抗菌剂及其在纺织材料上的应用研究进展[J].丝绸,2024,61(5):58-68.
[10] 郑建平,刘禹豪,张北波.锦纶6/纳米氧化亚铜复合纤维制备及性能[J].纺织科技进展,2024,46(3):25-29.
[11] 胡定军,刘朝军,章浩荣.聚丙烯单原子铜抗菌纤维的制备及其性能[J].工程塑料应用,2023,51(5):51-55.
[12] INKINEN J,MÄKINEN R,KEINÄNEN-TOIVOLA M M,et al.Copper as an antibacterial material in different facilities[J].Letters in Applied Microbiology,2017,64(1):29-39.
[13] 靳雨薇.高性能聚酰胺复合材料的制备及性能研究[D].银川:宁夏大学,2024.
[14] 王卉,王伟.抗菌尼龙6纤维的研究进展[J].广东化工,2023,50(14):74-75,79.
[15] 白玲.几种新型纤维材料的开发与应用[C]//第七届功能性纺织品及纳米技术应用研讨会论文集.北京:中国纺织科学研究院,2007:260-265.
[16] 田银彩,胡凌宵.聚酰胺6/短切碳纤维复合材料制备及力学性能 [J].工程塑料应用,2022,50(10):30-35.
基本信息:
DOI:10.19507/j.cnki.1673-0356.2026.03.005
中图分类号:TS156
引用信息:
[1]吴明珠,郭永梅,孟祥瑞.载铜分子筛-PA6纤维的制备及抗菌性能[J].纺织科技进展,2026,48(03):21-25.DOI:10.19507/j.cnki.1673-0356.2026.03.005.
基金信息:
2023年福建省大学生创新创业训练计划省级项目(S20231039-5059)
2025-03-03
2025
2025-04-16
2025-04-17
2025
1
2026-03-25
2026-03-25